If electrical conduction in mercury were purely electronic, there
should be no dependence upon the nuclear masses. This dependence of
the critical
temperature for superconductivity upon isotopic mass was the
first direct evidence for interaction between the electrons and the
lattice. This supported the BCS
theory of lattice coupling of electron
pairs.
It is quite remarkable that an electrical phenomenon like the
transition to zero resistivity should involve a purely mechanical
property of the lattice. Since a change in the critical temperature
involves a change in the energy environment associated with the
superconducting transition, this suggests that part of the energy is
being used to move the atoms of the lattice since the energy depends
upon the mass of the lattice. This indicates that lattice vibrations
are a part of the superconducting process. This was an important
clue in the process of developing the BCS theory because it
suggested lattice coupling, and in the quantum treatment suggested
that phonons were involved. |