!DOCTYPE HTML PUBLIC "-//W3C//DTD HTML 4.0 Transitional//EN"> Superconductivity

The Discovery of Superconductivity



H. K. Onnes, Commun. Phys. Lab.12,120, (1911)
H. Kamerlingh Onnes, after having successfully liquified helium in 1908, investigated the low temperature resistivity of mercury in 1911. The mercury could be made very pure by distillation, and this was important because the resistivity at low temperatures tends to be dominated by impurity effects. He found that the resistivity suddenly dropped to zero at 4.2K, a phase transition to a zero resistance state. This phenomenon was called superconductivity, and the temperature at which it occurred is called its critical temperature.
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Is the resistance zero, or just small?


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Lead as Superconductor

Evidence for zero resistance

Lead is a Type I superconductor with a critical temperature of 7.2 K. Although such superconductors can conduct currents with zero resistance, their usefulness is limited because of low critical magnetic fields. Above a certain current, the magnetic field created by the current drives the material into a normal resistive state.

If a current is generated in a superconducting lead ring, it will persist because of the zero resistivity. Currents have been maintained in lead rings for several years to test the zero resistance condition. An induced current in an ordinary metal ring would decay rapidly from the dissipation of ordinary resistance, but superconducting rings had exhibited a decay constant of over a billion years!

An exactly zero resistance implies a quantum effect - an energy gap. If the charge carriers do not interact with their environment to reduce their energy even a little bit, it must be because they can't - they are forbidden to by conservation of energy. This implies that there are no available quantum states within reach of the energy they have. The evidence for an energy gap was one of the steps which led to the BCS theory of superconductivity.


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Superconductivity Examples

Mercury Superconducting Transition



H. K. Onnes, Commun. Phys. Lab.12,120, (1911)
Mercury was historically the first to show superconductivity, and it is an example of a Type I superconductor. Its practical usefulness is limited by the fact that its critical magnetic field is only 0.019 T, so the amount of electric current it can carry is also limited.

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Niobium-Tin Superconductor



B. T. Matthias, et al., Phys. Rev. 95, 1435, (1954)

The superconducting transition of niobium-tin was observed by measuring the inductance of a coil which was wrapped around the sample. At the superconducting transition, the magnetic field is expelled by the Meissner effect and the inductance drops.

This measurement was made by immersing the coil in liquid hydrogen and measuring the inductance as a function of temperature.


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Lanthanum-Barium-Copper Oxide Superconductor



Bednorz and Muller, Z. Physik B64, 189, (1986)
This ceramic material was the first of a new class of high temperature superconductors. It is made by randomly substituting some barium atoms into the lattice of lanthanum- copper-oxide in what is termed a solid solution.

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Yttrium-Barium-Copper Oxide

This ceramic material was the first of the high temperature superconductors to make the phase change at a temperature above the liquid nitrogen temperature (77 K).


M. K. Wu, et al., Phys. Rev. 58, 908 (1987)

Structure and discussion
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Superconductivity